Poly-2,4,6,n-methylated undecene-(3–6) and pentadecene-derivatives(8–11) have been synthesized. In these compounds each backbone segment displays local bi-conformational behaviour. The effect of oxygen-substituents on the conformer population of the individual backbone segments has been studied by evaluating 3JH,H and 3JC,C coupling constants.
R. Göttlich, T. Fäcke, U. Rolle and R. W. Hoffmann, J. Chem. Soc., Perkin Trans. 2, 1996, 2059 DOI: 10.1039/P29960002059
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