New intercalation compounds of the pseudo-layered oxides UVITeIVO5 and UVISeIVO5 have been prepared and characterised. At ambient temperatures products of the type AxUMO5(x⩽ 1; A = Li, Na, H, NH4) are formed by both host oxides with minimal structural change. Magnetic susceptibility measurements confirm that UV species are formed on intercalation.
P. G. Dickens, E. P. Stradling, C. A. Bearchell and I. D. Fawcett, J. Mater. Chem., 1996, 6, 1211 DOI: 10.1039/JM9960601211
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