Issue 13, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Neutral five-co-ordinate gallium(III) and indium(III) complexes derived from sulfur ligands

Subrato Bhattacharya,   Neena Seth,   Dileep K. Srivastava,   Vishnu D. Gupta,   Heinrich Nöth  and  Martina Thomann-Albach  

Abstract

Five-co-ordinated gallium(III) and indium(III) complexes, GaCl[PhC(S)CHC(O)Ph]2, GaCl(S2CNR2)2(R = Me, Pri or NR2= pyrrolyl) and InCl(S2CNPri2)2, have been synthesized and characterized. X-Ray crystallographic studies revealed a trigonal-bipyramidal structure for GaCl[PhC(S)CHC(O)Ph]2 and square-pyramidal structures for GaCl(S2CNMe2)2 and InCl(S2CNPri2)2. Also, Ga(S2CNC4H4)3 has been synthesized. Its molecular structure shows a GaS6 core approaching a trigonal-prismatic geometry.

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Article information

DOI
https://doi.org/10.1039/DT9960002815
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 2815-2820

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Neutral five-co-ordinate gallium(III) and indium(III) complexes derived from sulfur ligands

S. Bhattacharya, N. Seth, D. K. Srivastava, V. D. Gupta, H. Nöth and M. Thomann-Albach, J. Chem. Soc., Dalton Trans., 1996, 2815 DOI: 10.1039/DT9960002815

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