Photoinduced dissociative electron capture of a sterically hindered m-phenylenebis(phosphinous chloride) in the presence of an electron-rich olefin at 110 K affords a novel triplet ground-state phosphinyl diradical which is fully characterised using EPR spectroscopy.
M. M. Wienk and R. A. J. Janssen, Chem. Commun., 1996, 1919 DOI: 10.1039/CC9960001919
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