Issue 11, 1996

Acceptor directionality of sterically unhindered C–H⋯O[double bond, length half m-dash]C hydrogen bonds donated by acidic C–H groups

Abstract

Crystal correlation study of acidic and sterically unhindered C–H groups (chloroform, dichloromethane and terminal alkynes) forming short contacts with carbonyl acceptors, reveals a soft but significant preference for the conventional carbonyl lone-pair direction.

Article information

Article type
Paper

Chem. Commun., 1996, 1277-1278

Acceptor directionality of sterically unhindered C–H⋯O[double bond, length half m-dash]C hydrogen bonds donated by acidic C–H groups

T. Steiner, J. A. Kanters and J. Kroon, Chem. Commun., 1996, 1277 DOI: 10.1039/CC9960001277

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