Issue 9, 1996

Tandem synthesis of polypropionate chains–highly stereoselective synthesis of the ansa chain of streptovaricin U and protostreptovaricins based on stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminium

Abstract

The highly stereoselective synthesis of the ansa chain segment 23 of streptovaricin U and protostreptovaricins (I and II) is achieved by stereospecific methylation of γ,δ-epoxy acrylates with trimethylaluminium.

Article information

Article type
Paper

Chem. Commun., 1996, 1027-1028

Tandem synthesis of polypropionate chains–highly stereoselective synthesis of the ansa chain of streptovaricin U and protostreptovaricins based on stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminium

M. Miyashita, T. Shiratani, K. Kawamine, S. Hatakeyama and H. Irie, Chem. Commun., 1996, 1027 DOI: 10.1039/CC9960001027

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