Correlated ab initio calculations identify the rate-determining step in the carbonylation reaction of palladium(II) complexes of mixed bidentate anionic ligands, and supply new evidence for the participation of five-coordinate intermediates and transition structure.
K. Frankcombe, K. Cavell, R. Knott and B. Yates, Chem. Commun., 1996, 781 DOI: 10.1039/CC9960000781
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