Issue 2, 1996

Synthesis of allyltitanium compounds by intramolecular nucleophilic acyl substitution reaction of alka-3,5-dienyl carbonates and their unusual regioselectivity in reaction with aldehydes

Abstract

Treatment of carbonates of alka-3,5-dien-1-ols with (η2-propene)Ti(OPri)2 resulted in intramolecular nucleophilic acyl substitution (INAS) reaction to afford allyltitanium compounds containing lactone or ester moieties, which add regiospecifically to aldehydes.

Article information

Article type
Paper

Chem. Commun., 1996, 197-198

Synthesis of allyltitanium compounds by intramolecular nucleophilic acyl substitution reaction of alka-3,5-dienyl carbonates and their unusual regioselectivity in reaction with aldehydes

P. K. Zubaidha, A. Kasatkin and F. Sato, Chem. Commun., 1996, 197 DOI: 10.1039/CC9960000197

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