Neutral carriers, such as 16-crown-5 and calix[4]arene tetraester, were immobilized on silicone-rubber membranes by covalent bonding. Sodium ion-selective electrodes based on silicone-rubber membranes modified chemically by the calixarene ionophore together with an anion excluder exhibited high performance in terms of sensitivity, selectivity and response time.
Y. Tsujimura, T. Sunagawa, M. Yokoyama and K. Kimura, Analyst, 1996, 121, 1705 DOI: 10.1039/AN9962101705
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