Issue 4, 1995

Benzodiazepine analogues. Part 9. Kinetics and mechanism of the azidotrimethylsilane-mediated Schmidt reaction of flavanones

Abstract

1 H NMR spectroscopy has been used to monitor the formation of 1,4-benzoxazepinones and their [1,5-d]tetrazolo analogues via azidotrimethylsilane-mediated Schmidt rearrangement of flavanone precursors. Analysis of the kinetic data has permitted the determination of rate coefficients and rationalization of substituent effects.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1995, 835-838

Benzodiazepine analogues. Part 9. Kinetics and mechanism of the azidotrimethylsilane-mediated Schmidt reaction of flavanones

P. T. Kaye, M. J. Mphahlele and M. E. Brown, J. Chem. Soc., Perkin Trans. 2, 1995, 835 DOI: 10.1039/P29950000835

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