SCHEDULED MAINTENANCE:
Photoirradiation of the title compounds, Ar(CH2)nNHPh (Ar = 9-phenanthryl, n= 6–10, and 12), in benzene under anaerobic conditions gave polycyclic compounds with the 2-azabicyclo[3.3.1]nonane skeleton. It is proposed that the photoreaction proceeds by electron transfer via an exciplex to give polycyclic compounds as a result of the addition of the NH group to the phenanthrene ring.
A. Sugimoto, N. Fukada, T. Adachi and H. Inoue, J. Chem. Soc., Perkin Trans. 1, 1995, 1597 DOI: 10.1039/P19950001597
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