Issue 4, 1995

Rearrangement of S-methylbenzylsulfonium S-alkylides in non-basic media

Abstract

S-Methyibenzylsulfonium S-alkylides, prepared by fluoride ion-induced desilylation of S-methyl-S-[1-(trimethylsilyl)alkyl](2,4-disubstituted benzyl)sulfonium salts 8 in dimethyl sulfoxide, rearranged exclusively to Sommelet–Hauser products without contamination of Stevens products.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1995, 431-435

Rearrangement of S-methylbenzylsulfonium S-alkylides in non-basic media

T. Tanzawa, M. Ichioka, N. Shirai and Y. Sato, J. Chem. Soc., Perkin Trans. 1, 1995, 431 DOI: 10.1039/P19950000431

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