The reaction of chiral TiIV amide-homoenolates with aromatic aldehydes gave syn-adducts predominantly, whereas the corresponding ZnZnII reagents in the presence of chlorotrimethylsilane gave the anti-adducts preferentially.
S. Sakami, T. Houkawa, M. Asaoka and H. Takei, J. Chem. Soc., Perkin Trans. 1, 1995, 285 DOI: 10.1039/P19950000285
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