Incubation of the substrate analogue, (3S)-(E,E,E,E,E)-10,15-diethyl-2,6,19,23-tetramethyl-2,3-epoxytetracosa-6,10,14,18,22-pentaene (–)-1, with 2,3-oxidosqualene–lanosterol cyclase from pigs liver gave unprecedented cyclization products 2 and 3 having a monocyclic skeleton.
T. Hoshino, E. Ishibashi and K. Kaneko, J. Chem. Soc., Chem. Commun., 1995, 2401 DOI: 10.1039/C39950002401
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