Generated in situ, the parent allyl vinyl sulfonium ion rapidly undergoes the title rearrangement to give a γ,δ-unsaturated thionium ion; a similar process appears to be involved in the reaction of phenyl vinyl sulfoxide with isobutene.
J. N. Harvey and H. G. Viehe, J. Chem. Soc., Chem. Commun., 1995, 2345 DOI: 10.1039/C39950002345
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