Use of preorganised donor-acceptor molecules for controlling and generating solid-state architecture is demonstrated by a molecule having donors and acceptors nearly orthogonal to each other which yields a superstructure composed of alternating layers of donor–acceptor columns of different orientations upon cocrystallisation with TCNQ.
J. Otsuki, T. Oya, S. Lee and K. Araki, J. Chem. Soc., Chem. Commun., 1995, 2193 DOI: 10.1039/C39950002193
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