The alkylidyne tricobalt nonacarbonyl clusters [Co3(CO)9{C(CO)OCH2CH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2}]1 and [Co3(CO)9{C(CO)O(CH2)2O(CO)CHCH2}]2 are prepared; compound 2 readily undergoes polymerisation to form polyacrylate resins containing the CCo3(CO)9 unit intact, as shown by GPC/UV–VIS and IR spectroscopy.
B. F. G. Johnson, A. J. Blake, A. J. Brown, S. Parsons and P. Taylor, J. Chem. Soc., Chem. Commun., 1995, 2117 DOI: 10.1039/C39950002117
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