N-(Benzylidene)- and N-(alkylidene)-homoallylamines are cyclised by electrophiles, e.g. bromine or phenylselenenyl bromide, and by subsequent reduction to the corresponding 3-functionalised pyrrolidines; the stereochemistry was investigated, and reductive removal of the 3(or 4)-bromo- and 3(or 4)-phenylseleno-substituents was accomplished.
D. De Smaele and N. De Kimpe, J. Chem. Soc., Chem. Commun., 1995, 2029 DOI: 10.1039/C39950002029
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