Issue 16, 1995

Macropolyhedral boron-containing cluster chemistry—the nineteen-vertex oxaborane anion, [OB18H21]

Abstract

The first structurally characterised polyhedral oxaborane species, the macropolyhedral anion [OB18H21], has been isolated (30–35%) from the reaction of water with the products of the reaction between anti-B18H22 and either Na or Na[BH4] in THF; the structure is based on the anti-B18H22 type of macropolyhedral cluster, with an oxygen atom between the B(8) and B(9) positions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1665-1666

Macropolyhedral boron-containing cluster chemistry—the nineteen-vertex oxaborane anion, [OB18H21]

T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1995, 1665 DOI: 10.1039/C39950001665

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