1,1-Bis-(2-aminoethyl)hydrazine condenses with formaldehyde to a polymer that is isomerized to the nonacyclic title compound, showing increased conformational mobility and crystallizing as a tetrahydrate for which the X-ray analysis reveals channels formed by stacked rings and filled by chains of water molecules.
J. Dale, C. Rømming and M. R. Suissa, J. Chem. Soc., Chem. Commun., 1995, 1633 DOI: 10.1039/C39950001633
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