Issue 15, 1995

Synthesis and magnetism of mixed valency [N(n-C4H9)4 or P(C6H5)4]CrIICrIII(C2O4)3

Abstract

Mixed valency compounds ACrIICrIII(C2O4)3[A = N(n-C4H9)4, P(C6H5)4] have been synthesised and characterised structurally and magnetically, the structures consisting of hexagonal layers of Cr bridged by C2O42–; although short range antiferromagnetic correlations are observed below 100 K no transition to a long range ordered state is observed above 2 K.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1513-1514

Synthesis and magnetism of mixed valency [N(n-C4H9)4 or P(C6H5)4]CrIICrIII(C2O4)3

C. J. Nuttall, C. Bellitto and P. Day, J. Chem. Soc., Chem. Commun., 1995, 1513 DOI: 10.1039/C39950001513

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