Reactions of primary amines with the perfluorovinyl complex [{Fe(CO)3}2{µ-C(SMe)(CF3)CCF2}]1 proceed with cleavage of two C–F bonds to give 2, whereas with secondary amines fluorine migration and C–F bond rupture afford the novel organometallic complex 3; both 2 and 3 have been characterized by X-ray analysis.
R. Rumin, F. Y. Pétillon, L. Manojlović-Muir, K. W. Muir and D. S. Yufit, J. Chem. Soc., Chem. Commun., 1995, 1431 DOI: 10.1039/C39950001431
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...