New stable nitroxides, analogous to TEMPO (tetramethylpiperidine-N-oxyl) where two α,α′ methyl groups are formally replaced by ester functions, are prepared via dienolate chemistry followed by a deprotection–oxidation sequence.
J. Einhorn, C. Einhorn, F. Ratajczak and J. Pierre, J. Chem. Soc., Chem. Commun., 1995, 1029 DOI: 10.1039/C39950001029
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