Synthesis and preliminary studies on the aggregation and non-linear optical properties of novel, highly soluble, free and transition metal-complexed triazolehemiporphyrazines 1 containing two 15-crown-5 subunits are reported; aggregation of the ‘crowned’ metallotriazolehemiporphyrazines induced by alkali cations is observed for the first time in these kinds of compounds.
F. Fernández-Lázaro, A. Sastre and T. Torres, J. Chem. Soc., Chem. Commun., 1995, 419 DOI: 10.1039/C39950000419
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