The X-ray crystal structures of palladium complexes 4 and 6 derived from (R)-N,N-dimethyl-1-(1-naphthyl)ethylamine and (S)-N,N-dimethyl-1-phenylethylamine, respectively, are reported; in the latter case two diastereoisomers differing both in the ligand configuration and the conformation of the C,N-chelate ring cocrystallise as a quasiracemate.
N. W. Alcock, D. I. Hulmes and J. M. Brown, J. Chem. Soc., Chem. Commun., 1995, 395 DOI: 10.1039/C39950000395
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