The homoleptic 3-thiapentane-1,5-dithiolato vanadium(III) complex [Li(thf)][V(tpdt)2]1 is synthesized and structurally characterized which reveals that 1 has an intriguing zigzag chain structure in the solid state where lithium cations bridge the tpdt sulfurs.
H. Kawaguchi, K. Tatsumi and A. Nakamura, J. Chem. Soc., Chem. Commun., 1995, 111 DOI: 10.1039/C39950000111
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