Issue 14, 1994

Novel modifications of the structure of the layered vanadyl hydrogenphosphate VO(HPO4)·0.5H2O

Abstract

The addition of metal ions such as Zn2+, Ni2+ and Pd2+ during the preparation of the layered vanadyl hydrogenphosphate VO(HPO4)·0.5H2O in aqueous media led to the formation of a new phase which is very different from that of the parent compound. This phase, which appears to be structurally similar to the vanadium(V) phosphate VO(PO4)·2H2O, is a mixed-valent vanadium compound with an expanded c-axis spacing in which the incorporated metal ions, in their divalent state, appear to be lodged in the interlayer region.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 2145-2149

Novel modifications of the structure of the layered vanadyl hydrogenphosphate VO(HPO4)·0.5H2O

A. Datta, R. Y. Kelkar and A. R. Saple, J. Chem. Soc., Dalton Trans., 1994, 2145 DOI: 10.1039/DT9940002145

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