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DOI: 10.1039/C39940002755 (Paper) Reference Section for: J. Chem. Soc., Chem. Commun., 1994, 2755-2756

Interpenetrating diamondoid frameworks of silver(I) cations linked by N,N′-bidentate molecular rods

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Lucia Carlucci, Gianfranco Ciani, Davide M. Proserpio and Angelo Sironi

Abstract

Three novel coordination polymers, [Ag(N–N)2]X (N–N = 4,4′-bipyridyl, X = CF3SO3––1; N–N = 4-cyanopyridine, X = BF4–, in two polymorphs, 2 and 3)], are prepared and investigated by single crystal X-ray analysis; 1 and 2 contain three-dimensional cationic frameworks, both consisting of four equivalent interpenetrating diamondoid lattices, while 3 is formed by two-dimensional layers of distorted squares.

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