α(o-Bromoanilino)alkenenitriles are converted to 2-(methylamino)benzonitrile and varied γ-carbolines by catalysis with palladium; the reactions may involve intramolecular aryl additions to the cyano group and other processes such as cyano group transposition, electrocyclisation, ethyl group transfer and oxidative aromatisation.
C. Yang, P. Sun and J. Fang, J. Chem. Soc., Chem. Commun., 1994, 2629 DOI: 10.1039/C39940002629
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