Terminal alkynes and allyl alcohol are coupled, with carbon–carbon bond formation, in the presence of a RuIV(C5Me5) catalyst, to give γδ-unsaturated acetals and with [{RuCl(C5Me5)}4] or [RuCl(cod)(C5Me5)] preferentially to produce the branched γ,δ-unsaturated aldehydes.
S. Dérien and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1994, 2551 DOI: 10.1039/C39940002551
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