Acetals of prop-2-ynal undergo double carbonylation with concomitant cleavage of an alkoxy group and stereoselective isomerisation to a vinyl ether under the catalytic action of a palladium iodide complex with thiourea.
A. Bonardi, M. Costa, B. Gabriele, G. Salerno and G. P. Chiusoli, J. Chem. Soc., Chem. Commun., 1994, 2429 DOI: 10.1039/C39940002429
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