The stable salt 2 is obtained from the reaction of SO2Cl2 with the imidazol-2-ylidene 1; the pyramidal structure of the chlorosulfite anion is confirmed both by X-ray structure and MO calculation.
N. Kuhn, H. Bohnen, D. Bläser, R. Boese and A. H. Maulitz, J. Chem. Soc., Chem. Commun., 1994, 2283 DOI: 10.1039/C39940002283
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