Irradiation of Iaevoglucosenone derivatives 5 in benzene affords unexpected products 6, which are formed via extrusion of carbon dioxide from intermediate dioxycarbenes.
S. Yamada, H. Ishikawa and M. Matsumoto, J. Chem. Soc., Chem. Commun., 1994, 2155 DOI: 10.1039/C39940002155
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