Issue 18, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and structure of [{TcVN(thiourea)}4(edta)2]·6H2O: the first example of a cyclic nitrido-bridged tetrameric technetium complex

John Baldas,   Silvano F. Colmanet,   Zlata Ivanov  and  Geoffrey A. Williams  

Abstract

The complex [{TcN(thiourea)}4(edta)2]·6H2O has been prepared and is shown to consist of a cyclic tetrameric Tc4N4 configuration with four asymmetrical Tc[triple bond, length half m-dash]N–Tc bridges; each diagonal pair of Tc atoms is bridged by an edta4–ligand and Tc[triple bond, length half m-dash]N distances range between 1.681(7) and 1.695(7)Å, with N–Tc of 1.977(7) to 2.009(7)Å.

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Article information

DOI
https://doi.org/10.1039/C39940002153
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2153-2154

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Preparation and structure of [{TcVN(thiourea)}4(edta)2]·6H2O: the first example of a cyclic nitrido-bridged tetrameric technetium complex

J. Baldas, S. F. Colmanet, Z. Ivanov and G. A. Williams, J. Chem. Soc., Chem. Commun., 1994, 2153 DOI: 10.1039/C39940002153

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