Spectroscopic and kinetic studies of β-cyclodextrin-linked L- and D-phenylalanine cyanoethyl esters in aqueous solution reveal an unusual intramolecular complexation mode where the hydrophobic portion of the amino acid resides outside the host cavity; L- and D-derivatives show different binding geometries and energies.
A. V. Eliseev, G. A. Iacobucci, N. A. Khanjin and F. M. Menger, J. Chem. Soc., Chem. Commun., 1994, 2051 DOI: 10.1039/C39940002051
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