Kinetic studies on the substitution reactions of [Fe2S2Cl3(NCMe)]– with the nucleophiles L = Br– or RS–(R = Et or But) to form [Fe2S2Cl3L]2– show that the rate of the reaction is inhibited by increasing the concentration of the nucleophile; this is a consequence of L binding to the iron atom not undergoing substitution.
R. A. Henderson and K. E. Oglieve, J. Chem. Soc., Chem. Commun., 1994, 1961 DOI: 10.1039/C39940001961
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