The oxathioether crown 1,4,7,10-tetraoxa-13,16-dithiacyclooctadec-14-en-14,15-dicarbonitrile reacts with HgCl2 to give an endocyclic complex in which macrocylic coordination to HgII in the solid state is through only the O donor atoms.
J. W. Sibert, S. J. Lange, C. Stern, B. M. Hoffman and A. G. M. Barrett, J. Chem. Soc., Chem. Commun., 1994, 1751 DOI: 10.1039/C39940001751
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