Interwoven two- and three-dimensional coordination polymers through self-assembly of CuI cations with linear bidentate ligands

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Leonard R. MacGillivray, S. Subramanian and Michael J. Zaworotko


Abstract

The synthesis and single crystal X-ray structures are reported of two interwoven cationic frameworks that are based upon tetrahedral and trigonal CuI ions; the resulting architectures are diamondoid, [CuI(bipy)2(PF6)](bipy = 4,4′-bipyridyl)1, and honeycomb, [CuI)2(pz)3(SiF6)](pz = pyrazine)2, respectively.


References

  1. P. J. Fagan and M. D. Ward, Scientific American, 1992, 48 Search PubMed .
  2. G. R. Desiraju, in Crystal Engineering: Design of Organic Solids, Elsevier, Amsterdam, 1989. Search PubMed .
  3. R. Robson, B. F. Abrahams, S. R. Batten, R. W. Gable, B. F. Hoskins and J. Liu, Supramolecular Architecture, ch. 19, ACS publications, 1992. Search PubMed .
  4. S. Mann, J. Chem. Soc., Dalton Trans., 1993, 1 RSC .
  5. B. F. Abrahams, B. F. Hoskins and R. Robson, J. Am. Chem. Soc., 1991, 113, 3603 CrossRef .
  6. B. F. Abrahams, B. F. Hoskins and R. Robson, J. Chem. Soc., Chem. Commun., 1990, 60 RSC ; T. Kitazawa, S. Nishikiori, R. Kurodo and T. Iwamoto, Chem. Lett., 1988, 1729 CAS ; T. Kitazawa, S. Nishikiori, A. Yamagishi, R. Kuroda and T. Iwamoto, J. Chem. Soc., Chem. Commun., 1992, 413 RSC .
  7. R. W. Gable, B. F. Hoskins and R. Robson, J. Chem. Soc., Chem. Commun., 1990, 1677 RSC .
  8. K.-W. Kim and M. G. Kanatzidis, J. Am. Chem. Soc., 1992, 114, 4878 CrossRef CAS .
  9. A. Michaelides, V. Kirtisis, S. Skoulika and A. Aubry, Angew. Chem., Int. Ed. Engl., 1993, 32, 1495 CrossRef .
  10. J. S. Lindsey, J. New. Chem., 1991, 15, 153 Search PubMed .
  11. S. B. Copp, S. Subramanian and M. J. Zaworotko, J. Am. Chem. Soc., 1992, 114, 8719 CrossRef CAS .
  12. S. B. Copp, S. Subramanian and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1993, 1078 RSC .
  13. Copper(I) complexes by F. H. Jardine, in Adv. Inorg. Chem. Radiochem., ed. H. J. Emeleus and A. G. Sharpe, vol. 17, Academic Press, 1975. Search PubMed .
  14. B. G. Hathaway, D. J. Holah and J. D. Postlethwaite, J. Chem. Soc., 1961, 3215 RSC .
  15. T. Otieno, S. J. Rettig, R. C. Thompson and J. Trotter, Inorg. Chem., 1993, 32, 1607 CrossRef CAS .
  16. For example, tetrahedral and trigonal Cul have even been observed in the same compound: P. Ganis, U. Lepore and G. Paiaro, J. Chem. Soc., Chem. Commun., 1969, 1054 Search PubMed ; S. J. Lippard, D. F. Lewis and P. S. Welcker, J. Am. Chem. Soc., 1970, 92, 3805 RSC .
  17. Trigonal Cul has recently been encountered in a triple-helical Cul complex: K. T. Potts, C. P. Horwitz, A. Fessak, M. Keshavarz-K, K. E. Nash and P. J. Toscano, J. Am. Chem. Soc., 1993, 115, 10444 Search PubMed .
  18. S. Swaminathan and B. M. Craven, Acta Cryst., 1984, B40, 300 CAS  and refs. therein..
  19. D. J. Duchamp and R. E. Marsh, Acta Cryst., 1969, B25, 5 .
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