Issue 8, 1994

Medium-dependent trapping of diazoalkane intermediates during photolysis of diazirines

Abstract

Photolysis of an intimate mixture of methyl(phenyl)diazirine and N-methylmaleimide in the absence of solvent permits the diazoalkane intermediate to be trapped, whereas the equivalent reaction in solution gives only cyclopropanated adducts.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 961-962

Medium-dependent trapping of diazoalkane intermediates during photolysis of diazirines

P. Bennett, L. M. Harwood, J. Macro and A. McGregor, J. Chem. Soc., Chem. Commun., 1994, 961 DOI: 10.1039/C39940000961

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