Chemoselective monobromination reactions of 2,3-dialkylzirconacyclopentenes are highly reagent dependent; NBS or Br2 give alkenyl halide selectively, whereas CCl3Br or CBr4 give homoallylic halides with a high chemoselectivity.
T. Takahashi, K. Aoyagi and D. Y. Kondakov, J. Chem. Soc., Chem. Commun., 1994, 747 DOI: 10.1039/C39940000747
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