The novel, chiral phosphordiamidite, {N,O-(1R,2S)-MeNCHMeCHPhO}PN(SiMe3)2 containing deprotonated ephidrine has been shown to phosphonylate aldehydes readily to afford α-functionalised phosphonate esters with diasteroselectivities upto ca. 96%.
V. Sum, T. P. Kee and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1994, 743 DOI: 10.1039/C39940000743
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