The pyrrole-based cryptand L, has asymmetric conformation when coordinated to dicopper(I); one-electron oxidation yields a localized mixed-valence dicopper cryptate of the singly deprotonated ligand and two-electron oxidation a dicopper(II) cryptate of the triply deprotonated ligand; single crystal X-ray structure determination shows two different irregular sites for CuII.
Q. Lu, V. McKee and J. Nelson, J. Chem. Soc., Chem. Commun., 1994, 649 DOI: 10.1039/C39940000649
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...