Issue 4, 1994

Protonation of the iron–sulfur core in [Fe4S4X4]2–(X = Cl or Br): chemical precedent for the elementary reaction of the hydrogenases and nitrogenases

Abstract

Kinetic studies on [Fe4S4X4]2–(X = Cl or Br) show that the substitution of the first halide for thiolate is catalysed by protonation of the Fe4S4 cubane core, this is the first demonstration that these cores will bind protons.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 377-379

Protonation of the iron–sulfur core in [Fe4S4X4]2–(X = Cl or Br): chemical precedent for the elementary reaction of the hydrogenases and nitrogenases

R. A. Henderson and K. E. Oglieve, J. Chem. Soc., Chem. Commun., 1994, 377 DOI: 10.1039/C39940000377

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