Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbons

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A. Corma, M. T. Navarro and J. Pérez Pariente


An ultralarge pore titanium silicate with MCM-41 structure has been prepared by direct hydrothermal synthesis; this material gives rise to useful catalysts for the selective oxidation of small and large organic compounds.


References

  1. U. Romano, A. Esposito, F. Maspero, C. Neri and M. G. Clerici, in New Developments in Selective Oxidation, ed. G. Centi and F. Trifiro, Elsevier, Amsterdam, 1990, 33. Search PubMed.
  2. J. S. Reddy, R. Kumar and P. Ratnasamy, Appl. Catal., 1990, 58, L1 CrossRef CAS.
  3. M. G. Clerici, Appl. Catal., 1991, 68, 249 CrossRef CAS.
  4. G. Bellusi, A. Carati, M. G. Clerici, G. Meddinelli and R. Millini, J. Catal., 1992, 133, 220 CrossRef CAS.
  5. D. R. C. Huybrechts, L. De Bruycher and P. A. Jacobs, Nature, 1990, 345, 240 CrossRef CAS.
  6. T. Tatsumi, M. Nakamura, S. Negishi and H. Tominaga, J. Chem. Soc., Chem. Commun., 1990, 476 RSC.
  7. M. A. Camblor, A. Corma and J. Pérez-Pariente, SP. Pat., 9101798, 1991..
  8. M. A. Camblor, A. Corma, A. Martínez and J. Pérez-Pariente, J. Chem. Soc., Chem. Commun., 1992, 8 RSC.
  9. A. Corma, M. A. Camblor, P. Esteve, A. Martínez and J. Pérez-Pariente, J. Catal., in the press Search PubMed.
  10. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, Nature, 1992, 359, 710 CrossRef CAS; C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, J. Am. Chem. Soc., 1992, 114, 10834 CrossRef CAS.
  11. D. R. C. Huybrechts, I. Vaesen, H. X. Li and P. A. Jacobs, Catal. Lett., 1991, 8, 237 CAS.
  12. M. R. Boccuti, K. R. Rao, A. Zecchina, G. Leofanti and G. Petrini, in Structure and Reactivity of Surfaces, ed. C. Morterra, A. Zecchina and G. Costa, Elsevier, Amsterdam, 1989, 133. Search PubMed.
  13. F. Geobaldo, S. Bordiga, A. Zecchina, E. Gianello, G. Leofanti and G. Petrini, Catal. Lett., 1992, 16, 109 CrossRef CAS.
  14. A. Corma, M. T. Navarro and J. Pérez-Pariente, Spa. Pat. 9301327, 1993..