Saturated hydrocarbons are selectively transformed into the corresponding alkyl trifluoroacetates in good yields by treatment with hydrogen peroxide in trifluoroacetic acid in the presence of Rh salts at room temperature.
K. Nomura and S. Uemura, J. Chem. Soc., Chem. Commun., 1994, 129 DOI: 10.1039/C39940000129
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