Issue 5, 1993

Ionic dynamics in the rotator phase of n-alkylammonium chlorides (C6–C10), studied by 1H nuclear magnetic resonance, electrical conductivity and thermal measurements

Abstract

1 H NMR, electrical conductivity and thermal measurements have been performed on the rotator phase of n-alkylammonium chlorides CnH2n+1 NH3Cl (n= 6–10). Rapid two-dimensional self-diffusion and uniaxial rotation of the long rod-like cations were observed in all salts studied by measuring 1H NMR spin–lattice relaxation times T1 and T1ρ, indicating the highly disordered structure of the rotator phase. Marked ionic self-diffusion was detected in this phase by measuring a.c. electrical conductivity which increased to ca. 10–2 S m–1 near the respective melting temperatures. Analysing the NMR relaxation and conductivity data, it was found that the anions also diffuse in this phase to a similar extent to the cations. From the characteristic dynamic behaviour in this phase, together with the small melting entropies (<20 J K–1 mol–1) reported, the rotator phase can be considered to be a low-dimensional plastic crystal or an intermediate state between the plastic crystal and smectic liquid crystal.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans., 1993,89, 827-831

Ionic dynamics in the rotator phase of n-alkylammonium chlorides (C6–C10), studied by 1H nuclear magnetic resonance, electrical conductivity and thermal measurements

S. Iwai, M. Hattori, D. Nakamura and R. Ikeda, J. Chem. Soc., Faraday Trans., 1993, 89, 827 DOI: 10.1039/FT9938900827

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