Issue 15, 1993

Dalton communications. Crystal structure of [Na·3thf][Fe(CO)3(SePh)3] and [N(PPh3)2][Fe(CO)3(SePh)3]·0.5thf (thf = tetrahydrofuran): evidence for Na+⋯ sePh and long-range Na+⋯ FeII interactions

Abstract

The reaction between Na[HFe(CO)4] and (PhSe)2 Yielded Na[Fe(CO)3(SePh)3] which crystallized as [Na·3thf][Fe(CO)3(SePh)3] in which three tetrahydrofuran (thf) molecules and the [Fe(CO)3(SePh)3] anion surround the sodium cation; in the corresponding crystal structure of [N(PPh3)2][Fe(CO)3-(SePh)3]·0.5thf the cations and anions are discrete entities.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 2421-2422

Dalton communications. Crystal structure of [Na·3thf][Fe(CO)3(SePh)3] and [N(PPh3)2][Fe(CO)3(SePh)3]·0.5thf (thf = tetrahydrofuran): evidence for Na+⋯ sePh and long-range Na+⋯ FeII interactions

W. Liaw, C. Lai, C. Lee, G. Lee and S. Peng, J. Chem. Soc., Dalton Trans., 1993, 2421 DOI: 10.1039/DT9930002421

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