The remarkable stability of [Cu(dppf)(odppf)]BF4[dppf = 1,1′-bis(diphenylphosphino)ferrocene, odppf = 1,1′-bis(oxodiphenylphosphoranyl)ferrocene], characterized in the solid state by X-ray analysis and in solution by 31P NMR spectroscopy, reveals a marked borderline character of copper(I).
G. Pilloni, B. Corain, M. Degano, B. Longato and G. Zanotti, J. Chem. Soc., Dalton Trans., 1993, 1777 DOI: 10.1039/DT9930001777
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