The complexation of 1,10-phenanthroline-5,6-dione by transition metals increases the catalytic turnover frequency by a factor of up to 17 for the aerobic-chemical and a factor of 14 for the indirect electrochemical NAD+-regeneration for HLADH catalysed alcohol oxidations in comparison with the uncomplexed phenanthrolinediones.
G. Hilt and E. Steckhan, J. Chem. Soc., Chem. Commun., 1993, 1706 DOI: 10.1039/C39930001706
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