Short Cu–S bonds, induced by strong intramolecular NH ⋯ S hydrogen bonds, have been established by X-ray analysis, IR spectra, and EHMO calculations for (NEt4)2(CuI(o-pabt))3](o-pabt =o-pivaloylaminobenzenethiolato) and suggest an important role for this type of hydrogen bonding in blue copper proteins.
T. Okamura, N. Ueyama, A. Nakamura, E. W. Ainscough, A. M. Brodie and J. M. Waters, J. Chem. Soc., Chem. Commun., 1993, 1658 DOI: 10.1039/C39930001658
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